Commonly occurring product ions for PI(37:0/16:0) (View full structure)

m/zIon DescriptionStructure (click to enlarge)
1103.8472Precursor ion [M-H]-
941.7944Loss of inositol from [M-H]-
865.6175Loss of sn2 acyl chain as ketene (RCH=C=O) from [M-H]-
847.6070Neutral loss of sn2 RCOOH group from [M-H]-
703.5647Loss of sn2 acyl chain as ketene (RCH=C=O) and inositol from [M-H]-
685.5542Neutral loss of sn2 RCOOH group and inositol from [M-H]-
571.2889Loss of sn1 acyl chain as ketene (RCH=C=O) from [M-H]-
553.2783Neutral loss of sn1 RCOOH group from [M-H]-
549.5616sn1 RCOO- ion
409.2361Loss of sn1 acyl chain as ketene (RCH=C=O) and inositol from [M-H]-
391.2255Neutral loss of sn1 RCOOH group and inositol from [M-H]-
315.0487Glycerophosphoinositol -H2O
297.0381Glycerophosphoinositol -2H2O
259.0225Inositol phosphate ion
255.2330sn2 RCOO- ion
241.0119Inositol phosphate ion - H2O
223.0013Inositol phosphate ion - 2 H2O
152.9958Glycerol-3-phosphate ion with loss of H2O
96.9696H2PO4- ion (from phosphate)
78.9591PO3- ion (from phosphate)
Note: Structures of product ions may represent one of a number of possible isobaric molecules in some cases